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001 265881
016 _a000316526300041
022 _a0025-326X
040 _aNEU
041 _aeng
050 0 4 _aTD178
100 1 _9574712
_aAksu, A.
245 1 0 _aA new approach to determine the ratio of redox active species such as Se-IV/Se-VI and As-III/AS(V) in marine systems
_cA.Aksu, N.Balkıs, I.Salihoğlu
260 _bPergamon-Elsevıer Scıence Ltd,
_c2013.
520 _aThe ratio of redox active species contributes to the researches about marine systems in many ways. Are marine systems reductant or oxidant? For this purpose, redox active species are analyzed by using high technology instrumental analyzers such as AAS, ICP, and HPLC. Then, all ion pair species are compared to each by calculating their ratios. These technologies are very expensive, and it takes long time to obtain the results. In this study, we suggested a basic method by using pH and Eh. Therefore, the Nernst equation expression was rearranged by using relative hydrogen (rH) and electrostatic activity coefficient (F-el). Additionally, the ratio of the redox active ion pair species Se-IV/Se-VI and As-III/As-V was calculated. (C) 2012 Elsevier Ltd. All rights reserved.
650 0 _9572720
_aNear East University Article
650 0 _9572723
_aYakın Doğu Üniversitesi Makale
650 _9120214
_aEnvironmental sciences
650 _9574713
_aOxidation-reduction potential (orp);
650 _9574714
_aNernst equation;
650 _9574715
_aElectrostatic activity coefficient (F-el)
650 _9574716
_aSelenıum
773 _gFeb 2013, Volume:67, Issue: 1-2, Pages: 228-233
_tMarıne Pollutıon Bulletın
_x0025326X
856 _uhttp://library.neu.edu.tr:2048/login?url=http://dx.doi.org/10.1016/j.marpolbul.2012.11.002
942 _x1000005
_kTD0000178N492013
_cOED
999 _c242568